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Boosting the photoactivity of grafted titania: ultrasound-driven synthesis of a multi-phase heterogeneous nano-architected photocatalyst

2021-01-16 

#BiomassValorization   #ChemicalWarfareAgents   #OrganicPhaseGraftedTitaniumOxideNanoparticles   #Publications   #UltrasoundAssistedSynthesis  

Abstract

The herein presented low-power high-frequency (500 kHz) ultrasound-assisted precipitation synthesis (LPHF-US) led to a unique multiphase nano-structured titanium dioxide, grafted with oxygen-containing organic functionalities. The material exhibited a high porosity (surface area 326 m2/g and total pores volume 0.484 cm3/g) and heterogeneous surface chemistry.  In the used LPHF-US synthetic protocol the energy-demanding calcination step leading to crystallization is eliminated and an organic residue is simultaneously grafted to the surface. That organic residue affects the anatase nanocrystals size (4-7 nm), which are embedded in an amorphous titanium hydroxide network. This nanomaterial showed a superior performance as a heterogenous photocatalyst either in a gaseous phase by decomposing toxic vapors of chemical warfare agents (a mustard-gas surrogate), or in a liquid phase by selectively oxidizing benzyl alcohol, a model lignin-biomass derived compound. The grafted organic phase enhances the catalyst’s photoreactivity under visible light, by acting as a photosensitizer (antenna effect) and/or as a source of chromophores .

D.A. Giannakoudakis, A. Qayyum, D. Łomot, M. Besenhard, D. Lisovytskiy, T.J. Bandosz, and J.C. Colmenares. Advanced Functional Materials, 2007115. DOI: 10.1002/adfm.202007115

https://onlinelibrary.wiley.com/doi/10.1002/adfm.202007115


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