In this work, we have successfully synthesized a set of titania photocatalytic nanocomposites by the incorporation of different TiO2 content on wheat bran residues. The obtained catalysts were characterized by different techniques including UV-Vis spectroscopy, X‑ray diffraction (XRD), X‑ray photoelectron spectroscopy (XPS) and Transmission Electron Microscopy (TEM) while their photocatalytic activity was investigated in the oxidation of benzyl alcohol under UV light irradiation. Benzaldehyde yields were ca. 20%, with conversion in the systems of ca. 33% of benzyl alcohol by using 10%Ti-Bran catalyst, as compared to 33% yield to the target product (quantitative conversion of benzyl alcohol) using commercial pure TiO2 (P‑25). The photocatalytic activity results indicate that designed waste-derived nanomaterials with low TiO2 content can efficiently photocatalyze the conversion of benzyl alcohol with relative high selectivity towards benzaldehyde.
W. Ouyang, J.M. Reina, E. Kuna, A. Yepez, A.M. Balu, A.A. Romero, J.C. Colmenares and R. Luque. Journal of Environmental Management, 203 (2017). 768 – 773.
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